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All ICDP Publications with Abstracts

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203.
Oreshkina, Tatiana V.; Oberhaensli, Hedi
{Diatom turnover in the early Paleogene diatomite of the Sengiley section, middle Povolzhie, Russia: A response to the initial Eocene thermal maximum?}
{Causes and consequences of globally warm climates in the early Paleogene} Publisher Geological Society of America 012003
ISBN:
9780813723693

202.
Noble gases in olivine phenocrysts from drill core samples of the Hawaii Scientific Drilling Project (HSDP) pilot and main holes (Mauna Loa and Mauna Kea, Hawaii)
Althaus, Tilmann; Niedermann, Samuel
Geochemistry, Geophysics, Geosystems, 4 (1) 2003
ISSN: 15252027 Publisher: Blackwell Publishing Ltd
Abstract: [1] We have determined concentrations and isotopic compositions of all noble gases in olivine phenocrysts from the Hawaii Scientific Drilling Project (HSDP) drill core, comprising Mauna Loa lavas in the top 247 m and Mauna Kea lavas down to the preliminary depth of 3109 m. Our aim was to describe the long-term isotopic evolution of noble gases over a significant time fraction of the active life of a major Hawaiian volcano. The He isotopic signature displays a clear temporal trend: 3He/4He ratios increase from MORBlike 9 RA in the youngest lavas to 15 RA in the Mauna Loa section and from ̃7 RA to ̃12 RA in the subaerial Mauna Kea deposits. They remain close to 12 RA in most of the submarine Mauna Kea samples, except for a few excursions with 3He/4He ratios of up to 21 RA in borehole depths between 2000 and 2600 m. The average 3He/4He ratio of 12 RA is lower than that observed in recent eruptions of Kilauea and Loihi seamount and supports the idea of a concentrically zoned Hawaiian plume [Kurz et al., 1996]. The Ne isotopic signature does not show a temporal evolution. It remains plume-like (plotting close to the Loihi-Kilauea correlation line in a Ne three-isotope diagram) over the whole Mauna Kea section in those samples which are not dominated by air-like Ne. Maximum 20Ne/22Ne and 21Ne/22Ne ratios reach 12.10 ± 0.36 and 0.0360 ±0.0042, respectively. 40Ar/36Ar ratios vary widely between 360 and ̃3300 in the ≥1000°C release steps due to variable atmospheric contributions. In at least one sample, a 40Ar/ 36Ar ratio of 14,300 ±910 demonstrates the presence of a MORB-like Ar component. Kr and Xe isotopic compositions are atmospheric throughout. We discuss several possibilities on how to explain the isotopic trends of the noble gases and their correlation to other geochemical parameters. Simple admixture of MORB-like noble gases to the plume component cannot account for the observations. We favor a model involving early melt extraction from the outer plume sections, followed by radiogenic ingrowth and, possibly, some interaction with ambient mantle material. © 2003 by the American Geophysical Union.
201.
Fluid flow in the resurgent dome of Long Valley Caldera: Implications from thermal data and deep electrical sounding
Pribnow, D.F.C.; Schütze, C.; Hurter, S.J.; Flechsig, C.; Sass, J.H.
Journal of Volcanology and Geothermal Research, 127 (3-4) 329-345 2003
ISSN: 03770273 Publisher: Elsevier
Keywords: Cooling; High temperature effects; Sediment transport; Water, Magma chambers, Geothermal fields, caldera; electrical resistivity; fluid flow; geochemistry; hydrothermal fluid; thermal regime, California; Long Valley Caldera; United States

Abstract: Temperatures of 100°C are measured at 3 km depth in a well located on the resurgent dome in the center of Long Valley Caldera, California, despite an assumed >800°C magma chamber at 6-8 km depth. Local downflow of cold meteoric water as a process for cooling the resurgent dome is ruled out by a Peclét-number analysis of temperature logs. These analyses reveal zones with fluid circulation at the upper and lower boundaries of the Bishop Tuff, and an upflow zone in the metasedimentary rocks. Vertical Darcy velocities range from 10 to 70 cm a-1. A 21-km-long geoelectrical profile across the caldera provides resistivity values to the order of 100 to >103 Ωm down to a depth of 6 km, as well as variations of self-potential. Interpretation of the electrical data with respect to hydrothermal fluid movement confirms that there is no downflow beneath the resurgent dome. To explain the unexpectedly low temperatures in the resurgent dome, we challenge the common view that the caldera as a whole is a regime of high temperatures and the resurgent dome is a local cold anomaly. Instead, we suggest that the caldera was cooled to normal thermal conditions by vigorous hydrothermal activity in the past, and that a present-day hot water flow system is responsible for local hot anomalies, such as Hot Creek and the area of the Casa Diablo geothermal power plant. The source of hot water has been associated with recent shallow intrusions into the West Moat. The focus of planning for future power plants should be to locate this present-day flow system instead of relying on heat from the old magma chamber. © 2003 Elsevier B.V. All rights reserved.
200.
Modelling the thermal regime of permafrost and gas hydrate deposits to determine the impact of climate warming, mallik field area
Taylor, A.E.
Bulletin of the Geological Survey of Canada (544) 391-401 2003
ISSN: 00687626

Abstract: We apply a two-dimensional geothermal model to predict the permafrost and natural gas hydrate structure in theMallik field area, based on two paleoenvironmental scenarios deduced at otherwells in theMackenzieDelta area. ScenarioAindicated a subaerial history throughout theHolocene, and scenario B documented a several thousand year, subaqueous episode during theHolocene followed by recent subaerial exposure. The effects of these histories is limited largely to the 600mthick permafrost zone, with scenarioB predicting a substantial talik. The most defensible scenario can be resolved with ground temperatures or independent paleoenvironmental indicators. The effect of climatewarmingwill be apparent in awarming of the permafrost and, with marine transgression, creation of an underlying talik. Terrestrial methane hydrate deposits remain stable with increasing surface temperatures over several centuries, but the base of gas hydrate stability rises about 2 m after 300 years.
199.
A late quaternary diatom record of tropical climatic history from Lake Titicaca (Peru and Bolivia)
Tapia, Pedro M.; Fritz, Sherilyn C.; Baker, Paul A.; Seltzer, Geoffrey O.; Dunbar, Robert B.
Palaeogeography, Palaeoclimatology, Palaeoecology, 194 (1-3) 139 – 164 2003
Keywords: Bolivia; Lake Titicaca; Peru; Bacillariophyta; Chaetoceros; Chaetoceros muelleri; Chaetoceros muelleri; Cyclotella; Cyclotella andina; Cyclotella meneghiniana; Cyclotella stelligera; Cyclotella stelligera; biostratigraphy; diatom; lake level; Last Glacial Maximum; paleoclimate; Quaternary

Abstract: A composite high-resolution diatom stratigraphy from three piston cores and one box-core in the deep sub-basin of Lake Titicaca reveals large moisture variations during the past 30 kyr in the Altiplano region. Diatom sequences indicate orbital and millennial-scale variability in water level and salinity. The pelagic freshwater diatom species Cyclotella andina and Cyclotella stelligera dominate Glacial-age sediments, suggesting that the lake was above its present outlet, Generally, wet conditions continued until 11 000 cal yr BP, as indicated by high percentages of freshwater planktonic diatoms. Large pulses of benthic diatom species between about 11 000 and 10 000 cal yr BP suggest brief intervals of large-amplitude declines in lake level. During the early Holocene (10 000-8500 cal yr BP), a freshwater diatom assemblage suggests overflowing conditions. Pelagic freshwater diatoms are replaced ca, 8500 cal yr BP by the salinity-indifferent species Cyclotella meneghiniana and by benthic taxa, indicating the beginning of lake regression. During the mid-Holocene (6000-3500 cal yr BP), the abundance of the saline taxon Chaetoceros muelleri, coupled with high abundances of epiphytic and epipelic diatoms, indicates maximum salinity and lowest lake levels in the entire 30 000 year record. Lake transgression began ca. 4000 cal yr BP, and the lake achieved modern levels by about 1500 cal yr BP. These water-level changes imply changes in effective moisture, most likely resulting from large precipitation changes. Precipitation was high throughout the Last Glacial Maximum (21 000-18 000 cal yr BP), likely due to an enhanced South American Summer Monsoon during peak summer insolation in the Southern Hemisphere. In contrast, the mid-Holocene transition was dryer than today in association with an austral summer insolation minimum and the subsequent weakening of the summer monsoon. © 2003 Elsevier Science B.V. All rights reserved.
198.
A Look Inside the San Andreas fault at Parkfield Through Vertical Seismic Profiling
Chavarria, J.A.; Malin, P.; Catchings, R.D.; Shalev, E.
Science, 302 (5651) 1746-1748 2003
ISSN: 00368075
Keywords: Cracks; Earthquakes; Fluids; Scattering, Vertical seismic profiling (VSP), Seismology, geological structure; microearthquake; P-wave; S-wave; San Andreas Fault; vertical seismic profile, article; earthquake; electric resistance; geology; material state; priority journal; rock; sediment; United States, California; North America; Parkfield; United States

Abstract: The San Andreas Fault Observatory at Depth pilot hole is located on the southwestern side of the Parkfield San Andreas fault. This observatory includes a vertical seismic profiling (VSP) array. VSP seismograms from nearby micro-earthquakes contain signals between the P and S waves. These signals may be P and S waves scattered by the local geologic structure. The collected scattering points form planar surfaces that we interpret as the San Andreas fault and four other secondary faults. The scattering process includes conversions between P and S waves, the strengths of which suggest large contrasts in material properties, possibly indicating the presence of cracks or fluids.
197.
A vegetation and fire history of Lake Titicaca since the last glacial maximum
Paduano, Gina M.; Bush, Mark B.; Baker, Paul A.; Fritz, Sherilyn C.; Seltzer, Geoffrey O.
Palaeogeography, Palaeoclimatology, Palaeoecology, 194 (1-3) 259 – 279 2003
Keywords: Bolivia; Lake Titicaca; Peru; Apiaceae; Apiales; Cyperaceae; Plantago; Plantago; Poaceae; Polylepis; Polylepis; deglaciation; fire history; Last Glacial Maximum; paleoclimate; pollen; Quaternary; vegetation history

Abstract: Fine-resolution fossil pollen and charcoal analyses reconstruct a vegetation and fire history in the area surrounding Lake Titicaca (3810 m, Peru/Bolivia) since ca, 27 500 cal yr BP (hereafter BP). Time control was based on 26 accelerator mass spectrometer (AMS) radiocarbon dates. Seventeen AMS dates and 155 pollen and charcoal samples between ca. 17 500 BP and ca. 3100 BP allow a centennial-scale reconstruction of deglacial and early- to mid-Holocene events. Local and regional fire signals were based on the separation of two charcoal size fractions, ≥ 180 μm and 179-65 μm. Charcoal abundance correlated closely with the proportion of woody taxa present in the pollen spectra. Little or no pollen was detected in the sedimentary record prior to ca. 21 000 BP. Very cold climatic conditions prevailed, with temperatures suggested to be at least 5-8°C cooler than present. Increases in pollen concentration suggest initial warming at ca. 21 000 BP with a more significant transition toward deglaciation ca. 17 700 BP. Between 17 700 BP and 13 700 BP, puna brava is progressively replaced by puna and sub-puna elements. The most significant changes between the Pleistocene and the Holocene floras were largely complete by 13 700 BP, providing an effective onset of near-modern conditions markedly earlier than in other Andean records. Fire first occurs in the catchment at ca. 17 700 BP and becomes progressively more important as fuel loads increase. No evidence is found of a rapid cooling and warming coincident with the Younger Dryas chron. A dry event between ca. 9000 BP and 3100 BP, with a peak between 6000 and 4000 BP, is inferred from changes in the composition of aquatics, and the marsh community as pollen of Cyperaceae is replaced by Poaceae, Apiaceae, Plantago and the shrub Polylepis. Human disturbance of the landscape is evident in the pollen spectra after ca. 3100 BP with the appearance of weed species. © 2003 Elsevier Science B.V. All rights reserved.
196.
Alteration of hyaloclastites in the HSDP 2 phase 1 drill core1. Description and paragenesis
Walton, A.W.; Schiffman, P.
Geochemistry, Geophysics, Geosystems, 4 (5) 2003
ISSN: 15252027
Abstract: [1] The core from the Hawaii Scientific Drilling Project 2 Phase 1 provides a unique opportunity for studying the low-temperature alteration processes affecting basalt in suboceanic-island environments. In hyaloclastites, which make up about one half of the lower 2 km of this core (the portion that accumulated below sea level), these processes have resulted in zones of incipient, smectitic, and palagonitic alteration. The alteration of sideromelane in these hyaloclastites has four distinct outcomes: dissolution, replacement by two different textural varieties of smectite (i.e., reddened and green grain-replacive), and conversion to palagonite. All samples show evidence of the incipient stage of alteration, suggesting that every sample passed through that zone. However, most samples that show palagonitic alteration do not also show evidence of smectitic alteration and vice versa, suggesting these two outcomes represent divergent paths of alteration. Incipient alteration (1080 to 1335 m depth) includes fracturing and mechanical reduction of porosity from 40-45% to about 20-30%; growth of one form of pore-lining smectite; dissolution of sideromelane; and formation of sideromelane-grain replacements consisting of Fe-hydroxide-strained smectite, titaniferous nodules, and tubules. DNA-specific stains and morphological features indicate that tubules are the result of microbial activity. Smectitic alteration (1405 to 1573 m) includes growth of a second variety of pore-lining smectite, pore-filling and grain-replacing smectite, and cements of phillipsite and Ca-silicate minerals. Palagonitic alteration (1573 m to the deepest samples) includes replacement of margins of shards with palagonite and growth of pore-filling chabazite. The porosity is reduced by cementation to less than 4% at 1573 m. Porosity does not decrease further down hole, nor does the thickness of palagonite rims on shards increase through the zone of palagonitic alteration. In these samples, palagonite is not an intermediate alteration product in the development of smectite. Rather, in hyaloclastites from the HSDP core, palagonite has formed after all observed smectites. Current downhole temperatures at the boundaries between the three alteration zones are in the range from 12° to 15°C, suggesting that geochemical thresholds or vital effects, not temperature conditions, control different outcomes of alteration. © 2003 by the American Geophysical Union.
195.
Brief climate events in the sedimentary record of Lake Baikal between 130 and 70 kyr BP
Prokopenko, A.A.; Karabanov, E.B.; Kuz'min, M.I.; Williams, D.F.; Khursevich, G.K.
Geologiya i Geofizika, 44 (7) 623 – 637 2003
ISSN: 00167886

Abstract: The paper presents new biogenic silica (BiSi) and total organic carbon (TOC) data for the past 130 kyr from BDP-98 and BDP-96-2 cores, respectively, showing a distinct climate periodicity correlated with Late Pleistocene rhythms. The high-resolution sedimentary records from Lake Baikal allow approaching the problem of the length of the last interglacial and stability of its climate in the Northern Hemisphere. The Siberian archives for the interval of 70 to 130 kyr contain brief sub-Milankovitch millenial-scale excursions correlated with events in the high-resolution records of North Atlantic ice cores and European continental pollen sequences. The correlation of the mid-Eemian cooling about 122 kyr BP and the cold Montaigu event about 103 kyr BP with low production signals in the Baikal cores evidence for a climatic connection between the geographically distant North Atlantic, continental Europe, and continental Siberia regions. This connection was well pronounced during interglacials and interstadials and weak during the later glaciation. Rapid warm/cold transitions in the Baikal record, especially the Kazantsevo/Early Zyryanka transition, indicate that glaciation in Siberia began at 115-116 kyr BP, or 5-8 kyr earlier than in Europe and in the North Atlantic, as inferred from independent age models. The continuous climate record from Lake Baikal provides a solid stratigraphic background for detailed correlation of Siberian continental sections.
194.
Characteristic magnetic behavior of subaerial and submarine lava units from the Hawaiian Scientific Drilling Project (HSDP-2)
Kontny, A.; Vahle, C.; De Wall, H.
Geochemistry, Geophysics, Geosystems, 4 (2) 2003
ISSN: 15252027
Abstract: This study presents rock magnetic properties and the magnetic mineralogy of subaerial and submarine lava flows of Mauna Loa and Mauna Kea volcanoes collected from the 3109 m deep HSDP-2 drill hole in Hawaii. Three different groups of magnetic behavior are recognized in the subaerial lava flows related to the degree of high temperature oxidation during extrusion. Group 1 shows homogenous titanomagnetite with low Xmt, low Curie temperatures (TC: 100°-200°C) and weak median demagnetizing fields (< 20 mT). Further subdivision into 1a and 1b subgroups is based on the low temperature behavior of magnetic susceptibility (MS) and hysteresis loops, which indicate a contribution from ferrimagnetic Cr-Al spinel below ca.-160°C in the 1b-type samples. Group 2 samples, with exsolution lamellae of ilmenite in the titanomagnetites, have higher TC (480°-580°C) and higher coercive forces (20-40 mT). Group 3, the highest oxidation stage, is characterized by titanohematite-bearing assemblages with enhanced median demagnetizing fields (35-85 mT) and a significantly different low-temperature MS behavior. MS core logging shows a systematic variation occurs in the subaerial lava flows, directly related to the degree of high temperature oxidation and their flow morphology. Aa lava flows have higher mean MS than other lava flow types. Besides these factors, MS appears to be also affected by the magma composition of the various shield-building stages. Mauna Loa subaerial lava flows generally show lower mean susceptibilities (4.6 ± 3 × 10-3 SI) than subaerial Mauna Kea lava flows (9.8 ± 5 × 10-3 SI). As submarine lava flows show no group 3 assemblages no high temperature oxidation influenced these rocks. Some hyaloclastites and pillow breccias show low MS (< 1 × 10-3 SI), small amounts of nearly pure magnetite (TC = 580°C) and high coercive forces up to 110 mT suggesting single domain and/or superparamagnetic behavior. The controlling mechanism of the magnetic properties in the submarine lava units is the cooling and quenching rate of lava flows, which creates large grain size variations in titanomagnetites of varying compositions. Hydrothermal alteration, as described from ocean floor or Icelandic basalts, is not an important process that influences the magnetic properties in the ocean island basalts from the HSDP-2 drill hole. © 2003 by the American Geophysical Union.
193.
Erratum: Paleointensity in Hawaiian Scientific Drilling Project Hole (HSDP2): Results from submarine basaltic glass (Geochemistry, Geophysics, Geosystems (2003) 4:5 (1042) DOI:10.1029/2001GC000276)
Tauxe, L.; Love, J.J.
Geochemistry, Geophysics, Geosystems, 4 (5) 2003
ISSN: 15252027
192.
Finding fault
Lee, A.
Engineer, 292 (7638) 21-24 2003
ISSN: 00137758

Abstract: The project to determine the fault zone by San Andreas Fault Observatory at Depth (SAFOD) is discussed. The aim of the project is to drill straight into the heart of San Andreas Fault Zones and place sensors that will predict earthquake accurately. Engineers will be using SAFOD collected data to design roads and buildings to withstand the sort of earthquakes which they are going to expose.
191.
Earthquake locations and three-dimentional fault zone structure along the creeping section of the San Andreas fault near Parkfield, CA: Preparing for SAFOD
Thurber, C.; Roecker, S.; Roberts, K.; Gold, M.; Powell, L.; Rittger, K.
Geophysical Research Letters, 30 (3) 12-1 2003
ISSN: 00948276

Abstract: Arrival-time data from 453 local earthquakes and 6 explosions at Parkfield, CA, are inverted for earthquake locations and three-dimensional Vp and Vp/Vs structure. The structure is dominated by the velocity contrast across the SAF, with the southwest side about 20-25% faster, consistent with previous studies. Nearly all the earthquakes occur almost directly beneath the fault trace. We find high-Vp/Vs anomalies that correlate with low-resistivity features in a magnetotelluric model that are interpreted to represent fluids. We locate a magnitude 2 earthquake that is a potential target event for the final stage of SAFOD drilling, yielding a depth of 3.1 km below surface and an epicenter 100 m southwest of the fault trace. Nonlinear analyses indicate 95%-confidence relative and absolute uncertainties on the order of 500-700 m vertically and 200-300 m horizontally for this target earthquake.
190.
Geology and geochemistry of shallow drill cores from the Bosumtwi impact structure, Ghana
Boamah, Daniel; Koeberl, Christian
Meteoritics and Planetary Science, 38 (8) 1137 – 1159 2003
ISSN: 10869379 Publisher: University of Arkansas
Keywords: Bosumtwi Impact Structure; Ghana; breccia; ejecta; geochemistry; geological structure; impact structure; tektite

Abstract: The 1.07 Ma well-preserved Bosumtwi impact structure in Ghana (10.5 km in diameter) formed in 2 Ga-old metamorphosed and crystalline rocks of the Birimian system. The interior of the structure is largely filled by the 8 km diameter Lake Bosumtwi, and the crater rim and region in the environs of the crater is covered by tropical rainforest, making geological studies rather difficult and restricted to road cuts and streams. In early 1999, we undertook a shallow drilling program to the north of the crater rim to determine the extent of the ejecta blanket around the crater and to obtain subsurface core samples for mineralogical, petrological, and geochemical studies of ejecta of the Bosumtwi impact structure. A variety of impactite lithologies are present, consisting of impact glass-rich suevite and several types of breccia: lithic breccia of single rock type, often grading into unbrecciated rock, with the rocks being shattered more or less in situ without much relative displacement (autochthonous?), and lithic polymict breccia that apparently do not contain any glassy material (allochtonous?). The suevite cores show that melt inclusions are present throughout the whole length of the cores in the form of vesicular glasses with no significant change of abundance with depth. Twenty samples from the 7 drill cores and 4 samples from recent road cuts in the structure were studied for their geochemical characteristics to accumulate a database for impact lithologies and their erosion products present at the Bosumtwi crater. Major and trace element analyses yielded compositions similar to those of the target rocks in the area (graywacke-phyllite, shale, and granite). Graywacke-phyllite and granite dikes seem to be important contributors to the compositions of the suevite and the road cut samples (fragmentary matrix), with a minor contribution of Pepiakese granite. The results also provide information about the thickness of the fallout suevite in the northern part of the Bosumtwi structure, which was determined to be ≤15 m and to occupy an area of ∼1.5 km2. Present suevite distribution is likely to be caused by differential erosion and does not reflect the initial areal extent of the continuous Bosumtwi ejecta deposits. Our studies allow a comparison with the extent of the suevite at the Ries, another well-preserved impact structure.
189.
Late Quaternary clay mineral record in Central Lake Baikal (Academician Ridge, Siberia)
Fagel, N.; Boski, T.; Likhoshway, L.; Oberhaensli, H.
Palaeogeography, Palaeoclimatology, Palaeoecology, 193 (1) 159 – 179 2003
ISSN: 00310182
Keywords: Russian Federation; Bacillariophyta; clay mineral; illite; lacustrine deposit; paleoclimate; proxy climate record; Quaternary; smectite

Abstract: We investigated the mineralogical composition of two cores recovered on the Academician Ridge (Central Lake Baikal, Siberia). Sedimentological features show that the cores are unaffected by turbidity currents. However, hemipelagic deposition is not continuous, but intermittently disturbed by syn- or post-sediment reworking (e.g., bioturbation, slumps, faulting). Such modes of deposition are consistent with the complex uplift history of the ridge. Bulk mineralogy suggests that terrigenous sediment supplies are constant through glacial/interglacial stages, and diluted by diatom-rich intervals related to warmer interglacial stages. The core stratigraphy is based on the correlation of the diatom zonation and opal abundance with the marine oxygen isotope reference curve SPECMAP. The ∼8-m cores partly recover the last four interglacial/glacial cycles, i.e., since oxygen isotope stage 8. We test the use of clay minerals as a proxy for paleoclimatic reconstruction. The clays are more weathered during the diatom-rich intervals in agreement with warmer climate conditions. However, the mean clay composition does not change significantly through glacial/interglacial stages. This observation implies that, in the Academician Ridge sediments, a simple smectite/illite ratio (S/I) does not alone provide a reliable indicator of climatic variation. It reflects the complex clay assemblages, especially the smectite group, delivered to Central Lake Baikal. Smectites include primarily illite-smectite mixed layers, made of a mixture of montmorillonite and beidellite. According to their behavior after cation saturation, the illite-smectite mixed layers are primarily transformed smectites, with some neoformed smectites intermittently observed. In addition, Al-smectites occur in minor proportions. We conclude that the S/I ratio has a climatic significance only if it evolves in parallel with the weathering stage of the clays and is confirmed by a change in the composition of the smectites. © 2002 Elsevier Science B.V. All rights reserved.
188.
Mid-holocene climate change in Lake Bosumtwi, Ghana
Russell, James; Talbot, Michael R.; Haskell, Brian J.
Quaternary Research, 60 (2) 133 – 141 2003
ISSN: 00335894 Publisher: Academic Press Inc.
Keywords: Ghana; Lake Bosumtwi; aridity; Holocene; lacustrine deposit; nitrogen isotope; paleoclimate; paleolimnology

Abstract: Lake Bosumtwi is one of the most widely studied palaeoclimate archives in West Africa. Results from numerous AMS 14C dates of samples from four piston cores from Lake Bosumtwi show that an abrupt sedimentary transition from a mid-Holocene sapropel to calcareous laminated muds occurred at about 3200 cal yr B.P. High-resolution analyses of the nitrogen isotopic composition of organic matter across this transition confirm its abrupt nature, and suggest that the change may signal a step toward increased aridity and intensified surface winds that affected western equatorial Africa from Ghana to the Congo basin. Northern and Eastern Africa experienced a similar abrupt shift toward aridity during the late Holocene, but at about 5000 cal yr B.P., a difference in timing that illustrates the regional nature of climate changes during the Holocene and the importance of feedback mechanisms in regulating Holocene climate variability. Furthermore, an abrupt change at about 3000 cal yr B.P. occurs at several sites adjacent to the tropical and subtropical Atlantic, which may hint at major changes in the surface temperatures of the tropical Atlantic and/or Pacific at this time. © 2003 University of Washington. Published by Elsevier Inc. All rights reserved.
187.
Hawaiian hot spot dynamics as inferred from the Hf and Pb isotope evolution of Mauna Kea volcano
Janne, Blichert-Toft; Weis, Dominique; Maerschalk, Claude; Agranier, Arnaud; Albarède, Francis
Geochemistry, Geophysics, Geosystems, 4 (2) 2003
ISSN: 15252027
Abstract: The present work reports multiple collector inductively coupled plasma mass spectrometry (MC-ICPMS) measurements of the isotopic compositions of Hf and Pb in the first 3 km of the deep core retrieved by the Hawaii Scientific Drilling Project. The measurements cover all the samples from the standard geochemical reference set, glasses from the deep hole, and replicates from the pilot hole. Both Hf and Pb are less radiogenic in Mauna Loa compared to Mauna Kea. The transition between Mauna Kea and Mauna Loa lavas in the deep core is progressive for eHf and 208Pb/204Pb, but a sharp discontinuity is observed for 208Pb*/206Pb*. There is no correlation between the alkalinity of the samples and isotopic composition. In detail, the Hf isotope compositions of samples from the pilot hole are not all identical to those of the HSDP-2 core for samples retrieved from a similar depth, suggesting that steep topography existed at the time of emplacement or that a different eruptive sequence was recorded. The strong correlation between 208Pb*/206Pb* and 3He/ 4He (He data from M. D. Kurz et al. (Rapid helium isotopic variability in Mauna Kea shield lavas from the Hawaiian Scientific Drilling Project, submitted to Geochemistry Geophysics Geosystems, 2002)) requires the episodic incorporation of a component that resembles the basalts erupted by either Kilauea or the Loihi eruptive centers (this component is referred to as K/L). The data suggest that some 500 kyr ago, Mauna Kea was tapping a mantle source similar to that tapped by Kilauea today. Isotopic variability of Pb and He cannot be accounted for by radiogenic ingrowth in a closed system, but requires the mixing of mantle source components with distinct outgassing histories. The time series of isotopic and concentration data in Mauna Kea samples spanning about 350,000 years of age indicate the recurrence of geochemical patterns in the melting column. Ignoring the most recent alkalic samples, we find that the dominant fluctuations of eHf and 207Pb/204Pb correspond to a period of 50,000 years. For La/ Yb, Zr/Nb, 87Sr/ 86Sr, 206Pb/204Pb, 207Pb/ 206Pb, and 208Pb/206Pb, a dominant period of ca. 18,000 years is obtained. Once provision is made for the existence of harmonics, the consistency between the isotopic spectrum of the pilot hole and the HDSP-2 core is very good. The input of the K/L component does not seem to be periodic. We use these recurrence intervals in conjunction with the upwelling rate deduced from buoyancy flux and seismic evidence of the maximum dimension of scatterers to constrain the radius of the Hawaiian plume conduit to be in the range of 10-50 km and the upwelling velocity to be in the range of 0.13-3 m/yr. Plausible vertical length scales of heterogeneities in the conduit are 6.5-160 km. © 2003 by the American Geophysical Union.
186.
Lithium isotope geochemistry of the Hawaiian plume: Results from the Hawaii scientific drilling project and koolau volcano
Chan, L.-H.; Frey, F.A.
Geochemistry, Geophysics, Geosystems, 4 (3) 2003
ISSN: 15252027
Abstract: [1] We determined lithium isotopic compositions of Mauna Loa and Mauna Kea basalts from the 3.1 km drill hole of the Hawaiian Scientific Drilling Project (HSDP); for comparison Li isotopic ratios were also determined for basalts from Koolau volcano. These two suites of samples define geochemical extremes in the range of Hawaiian shield lavas. The 400 Ka record of Mauna Kea in the HSDP core shows temporal fluctuations between low δ7Li (̃4% relative to the L-SVEC standard) and high δ7Li (5-6%), suggesting that the source components in the Hawaiian plume are heterogeneous in Li isotopic composition. Based on SiO2 content and isotopic ratios of He, Li, Nd, Hf and Pb, three geochemical groups are identified in Mauna Kea lavas. Mauna Kea basalts between 1900 and 2500 mbsl have relatively low δ7Li of about 4%. They are low SiO2 lavas distinguished by the highest 3He/4He and 208Pb/204Pb, and low 176Hf/ 177Hf and 143Nd/144Nd. Like basalt from Loihi seamount, this Mauna Kea group is considered to originate from the core of the plume. Above 1900 mbsl, high δ7Li lavas with high SiO 2 contents appear in both the submarine and subaerial sections. They are marked by low 3He/4He and high 176Hf/177Hf. The 7Li-rich signature of some samples (δ7Li up to 5.7) is indicative of recycled oceanic crust in the plume. This magma group defines the Kea component. The low SiO2 lavas in the subaerial section have low δ7Li (̃4%), 3He/4He and 208Pb/204Pb. Their δ7Li values overlap the range of δ7Li in unaltered mid-ocean ridge basalt (MORB) and are consistent with upper mantle material entrained by the plume or contamination of plume-derived magmas by the Pacific lithosphere. The δ7Li of Koolau lavas mostly fall within the range of 4.5 ± 0.3%. Exceptions are two samples that have δ7Li of 2-3%. The lightest isotopic values may indicate subducted Li that was isotopically fractionated during slab dehydration. In contrast to other isotopic systems, most Koolau samples, however, resemble Mauna Kea samples in Li isotopic composition. Mauna Loa samples have δ7Li values of 3.5 to 4.9%, within the range of the Koolau and Mauna Kea lavas. Based on these data, the Loa trend volcanoes and Kea trend volcanoes have largely overlapping Li isotopic compositions. In summary, the Hawaiian plume is not highly variable in Li isotopic composition; δ7Li is typically ̃4% with perturbations by subducted components to lower and higher ratios (2.5 to 5.7%). The overlap of most Hawaiian basalt and MORB in their range of Li isotopic ratios suggests minor influence of recycled oceanic crust in the plume and perhaps similar Li isotopic ratios in the upper and lower mantle. © 2003 by the American Geophysical Union.
185.
Late Quaternary lake-level changes constrained by radiocarbon and stable isotope studies on sediment cores from Lake Titicaca, South America
Rowe, Harold D.; Guilderson, Thomas P.; Dunbar, Robert B.; Southon, John R.; Seltzer, Geoffrey O.; Mucciarone, David A.; Fritz, Sherilyn C.; Baker, Paul A.
Global and Planetary Change, 38 (3-4) 273 – 290 2003
Keywords: Lake Titicaca; South America; geochronology; lake level; paleolimnology; radiocarbon dating; sediment core; stable isotope

Abstract: We present and compare AMS-14C geochronologies for sediment cores recovered from Lake Titicaca, South America. Radiocarbon dates from three core sites constrain the timing of late Quaternary paleoenvironmental changes in the Central Andes and highlight the site-specific factors that limit the radiocarbon geochronometer. With the exception of mid-Holocene sediments, all cores are generally devoid of macrophyte fragments, thus bulk organic fractions are used to build core chronologies. Comparisons of radiocarbon results for chemically defined fractions (bulk decalcified, humate, humin) suggest that ages derived from all fractions are generally coherent in the post-13,500 yr BP time interval. In the pre-13,500 yr BP time interval, ages derived from humate extracts are significantly younger (300-7000 years) than ages from paired humin residues. Gross age incoherencies between paired humate and humin sub-fractions in pre-13,500 yr BP sediments from all core sites probably reflect the net downward migration of humates. Ages derived from bulk decalcified fractions at our shallow water (90 m) and deep water (230 m) core sites consistently fall between ages derived from humate and humin sub-fractions in the pre-13,500 yr BP interval, reflecting that the bulk decalcified fraction is predominantly a mixture of humate and humin sub-fractions. Bulk decalcified ages from the pre-13,500 yr BP interval at our intermediate depth core site (150 m) are consistently older than humate (youngest) and humin sub-fractions. This uniform, reproducible pattern can be explained by the mobilization of a relatively older organic sub-fraction during and after the re-acidification step following the alkaline treatment of the bulk sediment. The inferred existence of this 'alkali-mobile, acid-soluble' sub-fraction implies a different depositional/post-depositional history that is potentially associated with a difference in source material. While internally consistent geochronologies can be developed for the Lake Titicaca sequence using different organic fractions, mobile organic sub-fractions and fractions containing mobile sub-fractions should generally be avoided in geochronology studies. Consequently, we believe humin and/or bulk decalcified ages provide the most consistent chronologies for the post-13,500 yr BP interval, and humin ages provide the most representative ages for sedimentation prior to 13,500 yr BP interval. Using the age model derived from the deep water core site and a previously published isotope-based lake-level reconstruction, we present a qualitative record of lake level in the context of several ice-core records from the western hemisphere. We find the latest Pleistocene lake-level response to changing insolation began during or just prior to the Bølling/Allerød period. Using the isotope-based lake-level reconstruction, we also find the 85-m drop in lake level that occurred during the mid-Holocene was synchronous with an increase in the variability of ice-core δ18O from a nearby icecap, but was not reflected in any of the polar ice-core records recovered from the interior of Antarctica and Greenland. © 2003 Published by Elsevier B.V.
184.
Microstructures, petrofabrics and seismic properties of ultra high-pressure eclogites from Sulu region, China: Implications for rheology of subducted continental crust and origin of mantle reflections
Ji, Shaocheng; Saruwatari, Kazuko; Mainprice, David; Wirth, Richard; Xu, Zhiqin; Xia, Bin
Tectonophysics, 370 (1-4) 49 – 76 2003
ISSN: 00401951 Publisher: Elsevier B.V.
Keywords: China; Sulu Belt; eclogite; mantle; microstructure; petrofabric; rheology; seismic reflection; subduction

Abstract: Ultra high-pressure (UHP) eclogites from Sulu region (China) represent mafic components of the continental crust, which were first subducted to mantle depths greater than 100 km and then exhumed to the earth's surface. Detailed investigation of microstructures, chemical compositions, petrofabrics and seismic properties of the UHP eclogites can provide important information on the operating deformation mechanisms and rheology of subducted continental crust and on the origin of seismic reflections within the upper mantle. We present here results from field, optical and TEM observations, electron back-scattered diffraction (EBSD) measurements and numerical computations of the seismic properties of UHP eclogites collected from fresh surface outcrops at the drill site (Maobei, Donghai County, Jiangsu Province) of the Chinese Continental Scientific Drilling Program (CCSD). Two types of eclogites have been distinguished: Type-1 (coarse-grained) eclogites deformed by recovery-accommodated dislocation creep at the peak metamorphic conditions, and Type-2 (fine-grained) eclogites which are composed of reworked Type-1 materials during recrystallization-accommodated dislocation creep in shear zones which were active during the exhumation of the UHP metamorphic rocks. Both garnet and omphacite in these eclogites deformed plastically and the flow strength contrast between these two constituent minerals is apparently much less than an order of magnitude under the UHP metamorphic conditions. Plasticity of eclogites under UHP conditions can effectively facilitate channeled flow along the interplate shear zone. The preservation of the relict crustal materials within the continental lithosphere may produce regionally extensive, strong, seismic reflections in the upper mantle. This may explain the origin of mantle reflections observed in many areas of the world. © 2003 Elsevier B.V. All rights reserved.
183.
Investigating a 65-Ma-Old smoking gun: Deep drilling of the chicxulub impact structure
Dressler, B.O.; Sharpton, V.L.; Morgan, J.; Buffler, R.; Moran, D.; Smit, J.; Stäffler, D.; Urrutia, J.
Eos, 84 (14) 125+130 2003

182.
Inferences on the hydrothermal system beneath the resurgent dome in Long Valley Caldera, east-central California, USA, from recent pumping tests and geochemical sampling
Farrar, C.D.; Sorey, M.L.; Roeloffs, E.; Galloway, D.L.; Howle, J.F.; Jacobson, R.
Journal of Volcanology and Geothermal Research, 127 (3-4) 305-328 2003
ISSN: 03770273 Publisher: Elsevier
Keywords: Geochemistry; Metamorphic rocks; Mineral resources; Seismology, Hydrothermal circulation, Volcanoes, caldera; fluid flow; geochemistry; hydraulic property; hydrology; hydrothermal system; volcanism; well testing, California; Long Valley Caldera; United States

Abstract: Quaternary volcanic unrest has provided heat for episodic hydrothermal circulation in the Long Valley caldera, including the present-day hydrothermal system, which has been active over the past 40 kyr. The most recent period of crustal unrest in this region of east-central California began around 1980 and has included periods of intense seismicity and ground deformation. Uplift totaling more than 0.7 m has been centered on the caldera's resurgent dome, and is best modeled by a near-vertical ellipsoidal source centered at depths of 6-7 km. Modeling of both deformation and microgravity data now suggests that (1) there are two inflation sources beneath the caldera, a shallower source 7-10 km beneath the resurgent dome and a deeper source ∼15 km beneath the caldera's south moat and (2) the shallower source may contain components of magmatic brine and gas. The Long Valley Exploration Well (LVEW), completed in 1998 on the resurgent dome, penetrates to a depth of 3 km directly above this shallower source, but bottoms in a zone of 100°C fluid with zero vertical thermal gradient. Although these results preclude extrapolations of temperatures at depths below 3 km, other information obtained from flow tests and fluid sampling at this well indicates the presence of magmatic volatiles and fault-related permeability within the metamorphic basement rocks underlying the volcanic fill. In this paper, we present recently acquired data from LVEW and compare them with information from other drill holes and thermal springs in Long Valley to delineate the likely flow paths and fluid system properties under the resurgent dome. Additional information from mineralogical assemblages in core obtained from fracture zones in LVEW documents a previous period of more vigorous and energetic fluid circulation beneath the resurgent dome. Although this system apparently died off as a result of mineral deposition and cooling (and/or deepening) of magmatic heat sources, flow testing and tidal analyses of LVEW water level data show that relatively high permeability and strain sensitivity still exist in the steeply dipping principal fracture zone penetrated at a depth of 2.6 km. The hydraulic properties of this zone would allow a pressure change induced at distances of several kilometers below the well to be observable within a matter of days. This indicates that continuous fluid pressure monitoring in the well could provide direct evidence of future intrusions of magma or high-temperature fluids at depths of 5-7 km. © 2003 Elsevier B.V. All rights reserved.
181.
High-resolution MIS 11 record from the continental sedimentary archive of Lake Baikal, Siberia
Karabanov, Eugene B.; Prokopenko, Alexander A.; Williams, Douglas F.; Khursevich, Galina K.; Kuzmin, Mikhail I.; Bezrukova, Elena V.; Gvozdkov, Alexander N.
Geophysical Monograph Series, 137223 – 230 2003

180.
Hawaiian lava flows in the third dimension: Identification and interpretation of pahoehoe and ̀àa distribution in the KP-1 and SOH-4 cores
Katz, M.G.; Cashman, K.V.
Geochemistry, Geophysics, Geosystems, 4 (2) 2003
ISSN: 15252027
Abstract: Hawaiian lava flows are classified as pahoehoe or ̀àa by their surface morphology. As surface morphology reflects flow emplacement conditions, the surface distribution of morphologic flow types has been used to study the evolution and eruptive history of basaltic volcanoes. We extend this analysis to the third dimension by determining the distribution of flow types in two deep drill cores, the Scientific Observation Hole-4 (SOH-4) core, drilled near Kilauea's East Rift Zone (ERZ), and the pilot hole (Kahi Puka-1 (KP-1)) for the Hawaiian Scientific Drilling Project (HSDP), drilled through distal flows from Mauna Loa and Mauna Kea. Flows are classified using both internal structures and groundmass textures, with the latter useful when identification based on mesoscopic flow features (e.g., surface morphology and vesicle content and distribution) is ambiguous. We then examine the temporal distribution of pahoehoe and ̀àa flows in proximal (SOH-4) and distal (KP-1) settings. Sequence analysis shows that the two flow types are not randomly distributed in either core but instead are strongly clustered. The proximal SOH-4 core is dominated by thin pahoehoe flows (̃60% by volume), consistent with the common occurrence of surface-fed pahoehoe flows in near-vent settings. The distal KP-1 core has a high proportion of ̀àa (̃58% by volume), although the proportion of pahoehoe and̀àa varies dramatically throughout the Mauna Kea sequence. Thick inflated pahoehoe flows dominate when the drill site was near sea level, consistent with the numerous inflated pahoehoe fields on the current coastal plains of Kilauea and Mauna Loa. ̀Àa flows are abundant when the site was far above sea level. As slope increases from the coastal plains to Mauna Kea's flank, this correlation may reflect the combined effect of long transport distances and increased slopes on flow emplacement. These results demonstrate that flow type and thickness variations in cores provide valuable information about both vent location and local site environment. Observed variations in flow type within the KP-1 core raise interesting questions about feedback between volcano evolution and flow morphology and suggest that flow type is an important variable in models of volcano growth and related models for lava flow hazard assessment. © 2003 by the American Geophysical Union.
179.
Preservation of primary volcanic textures in the ultrahigh-pressure terrain of Dabie Shan
Oberhänsli, R.; Martinotti, G.; Schmid, R.; Liu, X.
Geology, 30 (8) 699 – 702 2002
ISSN: 00917613
Keywords: China; High pressure effects; Levees; Zeolites; Pillow lava; pillow lava; preservation; ultrahigh pressure metamorphism; volcanic feature; volcaniclastic deposit; Volcanoes

Abstract: Delicate primary volcanic features such as ash layers, volcaniclastic breccias, and pillow lavas with amygdaloidal rims have been identified in a terrigenous volcanosedimentary sequence forming part of the ultrahigh-pressure unit of the Dabie Shan, China. The presence of coesite relies in crosscutting dikes confirms an ultrahigh-pressure evolution for the entire sequence. Evaluation of the probable reaction history for zeolite compositions as supposed for the amygdaloidal rims reveals a scarcity of reactions at very high pressures. Such special conditions of low reactivity and fluid- conserving reactions, combined with a lack of directed stress, have allowed the remarkable preservation of these primary volcanic features despite deep subduction.